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Ethanol

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**Chemical Properties and Uses**:
– Ethanol has the chemical formula CH3OH.
– Justus Liebig coined the name ‘ethyl’ in 1834, and ‘ethanol’ was termed in 1892.
– It is used as an anesthetic, antiseptic, solvent for medications, and in over 700 liquid medicine preparations.
– Ethanol acts as an antidote for certain poisonings.
– It was historically used as a general anesthetic and is effective against bacteria, fungi, and viruses.

**Recreational and Medical Applications**:
– Ethanol is a commonly consumed psychoactive drug and a central nervous system depressant.
– It is legal for sale in most countries but is addictive and carcinogenic.
– Laws regulate the sale and consumption of alcoholic beverages.
– Ethanol can be administered as an antidote for specific poisonings.
– It is metabolized in the liver and stomach by ADH enzymes.

**Industrial and Fuel Applications**:
– Ethanol is widely used as engine fuel and a fuel additive.
– Brazil heavily relies on ethanol as engine fuel, and the US primarily uses E10 and E85 ethanol/gasoline mixtures.
– Ethanol reduces harmful tailpipe emissions and has a higher research octane number than gasoline.
– It was historically used in rocket fuels and is currently used in lightweight rocket-powered aircraft.
– Ethanol is attractive for fuel cells due to availability, cost, purity, and low toxicity.

**Household and Chemical Applications**:
– Ethanol is used in household heating, cooking, and as a versatile solvent in paints, tinctures, and personal care products.
– It is used in DNA and RNA purification through ethanol precipitation.
– Ethanol is a crucial industrial ingredient and a precursor for various organic compounds.
– It plays a significant role in chemical reactions and the production of ethyl halides, esters, and acetic acid.
– Ethanol is also used in the synthesis of ethyl amines.

**Physical and Natural Properties**:
– Ethanol is a volatile, colorless liquid with a slight odor that burns with a smokeless blue flame.
– It has a refractive index slightly higher than water and a triple point at 150 ± 20 K.
– Ethanol is miscible with water and many organic solvents, forming azeotropes at specific concentrations.
– It catches fire above its flash point and is considered flammable in concentrations above 2.35% by mass.
– Ethanol is a byproduct of yeast metabolism, found in overripe fruit, and produced during the germination of many plants.

Ethanol (Wikipedia)

Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula CH3CH2OH. It is an alcohol, with its formula also written as C2H5OH, C2H6O or EtOH, where Et stands for ethyl. Ethanol is a volatile, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. It is a psychoactive recreational drug, and the active ingredient in alcoholic drinks.

Ethanol
Full structural formula of ethanol
Full structural formula of ethanol
Skeletal formula of ethanol
Skeletal formula of ethanol
Ball-and-stick model of ethanol
Ball-and-stick model of ethanol
Space-filling model of ethanol
Space-filling model of ethanol
Names
Pronunciation /ˈɛθənɒl/
Preferred IUPAC name
Ethanol
Other names
  • Absolute alcohol
  • Alcohol
  • Cologne spirit
  • Drinking alcohol
  • Ethylic alcohol
  • EtOH
  • Ethyl alcohol
  • Ethyl hydroxide
  • Ethylene hydrate
  • Ethylol
  • Grain alcohol
  • Hydroxyethane
  • Methylcarbinol
Identifiers
3D model (JSmol)
3DMet
1718733
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.000.526 Edit this at Wikidata
787
KEGG
UNII
UN number UN 1170
  • InChI=1S/C2H6O/c1-2-3/h3H,2H2,1H3 checkY
    Key: LFQSCWFLJHTTHZ-UHFFFAOYSA-N checkY
  • InChI=1/C2H6O/c1-2-3/h3H,2H2,1H3
    Key: LFQSCWFLJHTTHZ-UHFFFAOYAB
  • OCC
Properties
C2H6O
Molar mass 46.069 g·mol−1
Appearance Colourless liquid
Odor wine-like, pungent
Density 0.78945 g/cm3 (at 20 °C)
Melting point −114.14 ± 0.03 °C (−173.45 ± 0.05 °F; 159.01 ± 0.03 K)
Boiling point 78.23 ± 0.09 °C (172.81 ± 0.16 °F; 351.38 ± 0.09 K)
Miscible
log P −0.18
Vapor pressure 5.95 kPa (at 20 °C)
Acidity (pKa) 15.9 (H2O), 29.8 (DMSO)
−33.60·10−6 cm3/mol
1.3611
Viscosity 1.2 mPa·s (at 20 °C), 1.074 mPa·s (at 25 °C)
1.69 D
Hazards
GHS labelling:
GHS02: Flammable GHS07: Exclamation mark GHS08: Health hazard
Danger
H225, H319, H360D
P210, P233, P240, P241, P242, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
3
0
Flash point 14 °C (Absolute)
Lethal dose or concentration (LD, LC):
  • 7060 mg/kg (oral, rat)
  • 3450 mg/kg (mouse)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1000 ppm (1900 mg/m3)
REL (Recommended)
TWA 1000 ppm (1900 mg/m3)
IDLH (Immediate danger)
3300 ppm
Safety data sheet (SDS)
Related compounds
Related compounds
Supplementary data page
Ethanol (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Ethanol is naturally produced by the fermentation process of sugars by yeasts or via petrochemical processes such as ethylene hydration. Historically it was used as a general anesthetic, and has modern medical applications as an antiseptic, disinfectant, solvent for some medications, and antidote for methanol poisoning and ethylene glycol poisoning. It is used as a chemical solvent and in the synthesis of organic compounds, and as a fuel source. Ethanol also can be dehydrated to make ethylene, an important chemical feedstock. As of 2006, world production of ethanol was 51 gigalitres (1.3×1010 US gallons), coming mostly from Brazil and the U.S.

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